Using Differentiation
Velocity is the rate of change of displacement, and acceleration is the rate of change of velocity — so differentiating once or twice turns s(t) into everything else you need to know about the motion.
The calculus chain
Velocity is the rate of change of displacement, and acceleration is the rate of change of velocity. Differentiating $s(t)$ once gives velocity, and differentiating again — equivalently, differentiating $v(t)$ once — gives acceleration.
$$v = \dfrac{ds}{dt} \qquad a = \dfrac{dv}{dt} = \dfrac{d^2s}{dt^2}$$
Going from $s$ to $v$ to $a$ needs no extra information beyond the expression for $s(t)$ itself — unlike integrating, no constant needs to be found.
Worked example 1
The particle is momentarily at rest at $t=2$ ($v=0$), but the acceleration there is a large $32\ \text{m s}^{-2}$ — so this is not a lasting stop, just the single instant where the direction of motion is about to change.
Speeding up or slowing down?
Comparing the signs of $v$ and $a$ at a given instant tells you not just the direction of travel, but whether the particle is speeding up or slowing down at that moment.
If $v$ and $a$ have the same sign at an instant, the particle is speeding up — the acceleration is reinforcing the direction of travel. If $v$ and $a$ have opposite signs, the particle is slowing down — the acceleration is working against the direction of travel.
Worked example 2
Assuming a positive acceleration always means "speeding up" — it only does if the velocity is also positive. A positive acceleration acting on a particle moving in the negative direction is actually slowing that particle down. Always compare the signs of $v$ and $a$ together, never look at $a$ in isolation.
Check yourself
A particle's displacement is $s = 2t^3 - 9t^2 + 5$ metres. Find its velocity and acceleration when $t=1$, and state whether it is speeding up or slowing down at that instant.
(Hint: differentiate twice, then compare the signs of v and a.)
$v = 6t^2-18t$, so $v(1) = 6-18=-12\ \text{m s}^{-1}$.
$a = 12t-18$, so $a(1) = 12-18=-6\ \text{m s}^{-2}$. Both negative — same sign — so the particle is speeding up at $t=1$.